Transformation of ammonium nitrogen and response characteristics of nitrifying functional genes in tannery sludge contaminated soil          下载免费PDF全文

Kong Xiang-ke  Zhang Zi-xuan  Wang Ping  Wang Yan-yan  Zhang Zhao-ji  Han Zhan-tao  Ma Li-sha 《地下水科学与工程》2022,10(3):223-232

High concentrations of ammonium nitrogen released from tannery sludge during storage in open air may cause nitrogen pollution to soil and groundwater. To study the transformation mechanism of NH₄⁺-N by nitrifying functional bacteria in tannery sludge contaminated soils, a series of contaminated soil culture experiments were conducted in this study. The contents of ammonium nitrogen (as NH₄⁺-N), nitrite nitrogen (as NO₂^?-N) and nitrate nitrogen (as NO₃^?-N) were analyzed during the culture period under different conditions of pollution load, soil particle and redox environment. Sigmodial equation was used to interpret the change of NO₃^?-N with time in contaminated soils. The abundance variations of nitrifying functional genes (amoA and nxrA) were also detected using the real-time quantitative fluorescence PCR method. The results show that the nitrification of NH₄⁺-N was aggravated in the contaminated silt soil and fine sand under the condition of lower pollution load, finer particle size and more oxidizing environment. The sigmodial equation well fitted the dynamic accumulation curve of the NO₃^?-N content in the tannery sludge contaminated soils. The Cr(III) content increased with increasing pollution load, which inhibited the reproduction and activity of nitrifying bacteria in the soils, especially in coarse-grained soil. The accumulation of NO₂^?-N contents became more obvious with the increase of pollution load in the fine sand, and only 41.5% of the NH₄⁺-N was transformed to NO₃^?-N. The redox environment was the main factor affecting nitrification process in the soil. Compared to the aerobic soil environment, the transformation of NH₄⁺-N was significantly inhibited under anaerobic incubation condition, and the NO₃^?-N contents decreased by 37.2%, 61.9% and 91.9% under low, medium and high pollution loads, respectively. Nitrification was stronger in the silt soil since its copy number of amoA and nxrA genes was two times larger than that of fine sand. Moreover, the copy numbers of amoA and nxrA genes in the silt soil under the aerobic environment were 2.7 times and 2.2 times larger than those in the anaerobic environment. The abundance changes of the amoA and nxrA functional genes have a positive correlation with the nitrification intensity in the tannery sludge-contaminated soil.  相似文献   

Holistic approach of GIS based Multi-Criteria Decision Analysis (MCDA) and WetSpass models to evaluate groundwater potential in Gelana watershed of Ethiopia          下载免费PDF全文

Niway Wondesen Fikade  Molla Dagnachew Daniel  Lohani Tarun Kumar 《地下水科学与工程》2022,10(2):138-152

Appropriate quantification and identification of the groundwater distribution in a hydrological basin may provide necessary information for effective management, planning and development of groundwater resources. Groundwater potential assessment and delineation in a highly heterogeneous environment with limited Spatiotemporal data derived from Gelana watershed of Abaya Chamo lake basin is performed, using integrated multi-criteria decision analysis (MCDA), water and energy transfer between soil and plant and atmosphere under quasi-steady state (WetSpass) models. The outputs of the WetSpass model reveal a favorable structure of water balance in the basin studied, mainly using surface runoff. The simulated total flow and groundwater recharge are validated using river measurements and estimated baseflow at two gauging stations located in the study area, which yields a good agreement. The WetSpass model effectively integrates a water balance assessment in a geographical information system (GIS) environment. The WetSpass model is shown to be computationally reputable for such a remote complex setting as the African rift, with a correlation coefficient of 0.99 and 0.99 for total flow and baseflow at a significant level of p-value<0.05, respectively. The simulated annual water budget reveals that 77.22% of annual precipitation loses through evapotranspiration, of which 16.54% is lost via surface runoff while 6.24% is recharged to the groundwater. The calibrated groundwater recharge from the WetSpass model is then considered when determining the controlling factors of groundwater occurrence and formation, together with other multi-thematic layers such as lithology, geomorphology, lineament density and drainage density. The selected five thematic layers through MCDA are incorporated by employing the analytical hierarchy process (AHP) method to identify the relative dominance in groundwater potential zoning. The weighted factors in the AHP are procedurally aggregated, based on weighted linear combinations to provide the groundwater potential index. Based on the potential indexes, the area then is demarcated into low, moderate, and high groundwater potential zones (GWPZ). The identified GWPZs are finally examined using the existing groundwater inventory data (static water level and springs) in the region. About 70.7% of groundwater inventory points are coinciding with the delineated GWPZs. The weighting comparison shows that lithology, geomorphology, and groundwater recharge appear to be the dominant factors influence on the resources potential. The assessment of groundwater potential index values identify 45.88% as high, 39.38% moderate, and 14.73% as low groundwater potential zones. WetSpass model analysis is more preferable in the area like Gelana watershed when the topography is rugged, inaccessible and having limited gauging stations.  相似文献   

Genetic model and exploration target area of geothermal resources in Hongtang Area,Xiamen, China          下载免费PDF全文

Liu Chun-lei  Lu Chen-ming  Li Ya-song  Hao Qi-chen  Cao Sheng-wei 《地下水科学与工程》2022,10(2):128-137

The geothermal resources in Fujian Province are mainly hydrothermal resources of medium-low temperature. To better understand the whole process and conditions of heat control in the middle and deep crust, this study focuses on the analysis of heat accumulation model in Hongtang Area of Xiamen, and the main conditions of the model such as faults and sags are explored and interpreted in detail by using gravity and wide-field electromagnetic methods. 4 main faults (F33, F2, F12 and HT-F1) and 10 secondary faults (HT-F2, HT-F3, HT-F4, HT-F5, HT-F6, HT-F7, HT-F8, HT-F9, HT-F10 and HT-F11) were inferred, and the distribution range of sags was delineated. The convective geothermal system is composed of four components: Heat source, geothermal reservoir, heat-conductive fault and heat retaining cover, which form a quaternary heat accumulation model. According to the model, the intersection of the main faults F12, HT-F1 and F33 can be delineated as the primary target area of geothermal exploration, while the intersection of the secondary faults (F12 and HT-F6; F12 and HT-F2; HT-F9, HT-F10 and F12; F12 and HT-F11; F33 and HT-F3; HT-F8 and HT-F3; HT-F2, HT-F10 and HT-F1) can be delineated as the secondary target area. Borehole DR01, which is located in the primary target area, shows that the water temperature increases from fast to slow in the depth range of 0–500 m, and stays at 36℃ below 500 m. The reliability of the heat accumulation model and the target area was tested via geothermal boreholes, which is of great significance to the exploitation and utilization of geothermal resources in Hongtang Area of Xiamen.  相似文献   

Evolution of the freeze-thaw cycles in the source region of the Yellow River under the influence of climate change and its hydrological effects          下载免费PDF全文

Liang Zhu  Ming-nan Yang  Jing-tao Liu  Yu-xi Zhang  Xi Chen  Bing Zhou 《地下水科学与工程》2022,10(4):322-334

As an important water source and ecological barrier in the Yellow River Basin, the source region of the Yellow River (above the Huangheyan Hydrologic Station) presents a remarkable permafrost degradation trend due to climate change. Therefore, scientific understanding the effects of permafrost degradation on runoff variations is of great significance for the water resource and ecological protection in the Yellow River Basin. In this paper, we studied the mechanism and extent of the effect of degrading permafrost on surface flow in the source region of the Yellow River based on the monitoring data of temperature and moisture content of permafrost in 2013–2019 and the runoff data in 1960–2019. The following results have been found. From 2013 to 2019, the geotemperature of the monitoring sections at depths of 0–2.4 m increased by 0.16°C/a on average. With an increase in the thawing depth of the permafrost, the underground water storage space also increased, and the depth of water level above the frozen layer at the monitoring points decreased from above 1.2 m to 1.2–2 m. 64.7% of the average multiyear groundwater was recharged by runoff, in which meltwater from the permafrost accounted for 10.3%. Compared to 1960-1965, the runoff depth in the surface thawing period (from May to October) and the freezing period (from November to April) decreased by 1.5 mm and 1.2 mm, respectively during 1992–1997, accounting for 4.2% and 3.4% of the average annual runoff depth, respectively. Most specifically, the decrease in the runoff depth was primarily reflected in the decreased runoff from August to December. The permafrost degradation affects the runoff within a year by changing the runoff generation, concentration characteristics and the melt water quantity from permafrost, decreasing the runoff at the later stage of the permafrost thawing. However, the permafrost degradation has limited impacts on annual runoff and does not dominate the runoff changes in the source region of the Yellow River in the longterm.  相似文献   

甘肃通渭“9·14”常河滑坡成因机理     

王浩杰  孙萍  韩帅  张帅  李晓斌  王涛  辛鹏  郭强 《现代地质》2021,35(3):732-743

2019年9月14日11时,受多日降雨影响,甘肃省定西市通渭县常家河镇小庄村发生大规模黄土滑坡,体积约800万m³。滑坡造成部分农田、公路及阳坡大桥损毁,直接经济损失约2 347.2万元。在对滑坡现场进行大量地面调查的基础上,通过无人机航拍、现场测绘、走访调查和数值模拟等手段对滑坡的变形破坏特征进行了分析,并在此基础上探讨了其成因机制。结果表明:斜坡体是在震裂、蠕变、软化、水动力等多种条件下按照一定的先后顺序由稳态逐步演化至失稳;该滑坡的失稳演化过程和灾变机制可以概括为原始斜坡(黄土、泥岩二元层状结构)-地震触发(滑坡堆积体、坡体震裂损伤)-蠕变弱化(层间剪切带、裂缝和落水洞扩展)-降雨激发(滑带软化、泥化,水压力作用)-失稳滑动(滑面贯通)5个阶段;由于长期的蠕变和雨水的渗透冲蚀,坡体上的落水洞和地下暗河十分发育,且是控制本次滑坡边界的关键因素;滑坡后缘和前缘变形剧烈,中部变形相对稍弱,推断该滑坡为受地形及地下水作用控制明显的牵引-推移式复合滑坡。  相似文献   

危地马拉翡翠宝石矿物学特征及其与缅甸翡翠的对比研究     

邢碧倩  施光海  张锦洪  龙楚  张昱  何立言  胡汝杰 《现代地质》2021,35(6):1769-1788

危地马拉目前已成为仅次于缅甸的第二大翡翠原料供应地。这两个产地翡翠辨别的需求愈发迫切,且应用意义较大。采用显微镜观察、电子探针分析及背散射电子照相获得危地马拉蓝水料翡翠的矿物成分及结构构造特征,结合两产地翡翠产出的大地构造环境、自然地理环境、原石特征与矿物成分特征等进行对比分析。总体上,危地马拉翡翠次生原石有一定的磨圆,呈次棱角状,“皮”(风化皮)厚度较薄,较少出现翻砂现象,由“皮”向里,极少甚至几乎不存在“红雾”。相对地,缅甸翡翠次生原石发育显著的球状风化,原石通常有较好的磨圆度,棱角状不明显,“皮”厚度可达数厘米,用手压磨有显著的翻砂现象, “皮”“肉”之间偶可见“红雾”。硬玉与绿辉石成分判别图显示危地马拉翡翠中硬玉和绿辉石呈相对富Ca、贫Na的特征,而缅甸翡翠中硬玉和绿辉石整体呈相对贫Ca、富Na的特征。在Fe含量上,危地马拉翡翠中硬玉的Fe含量较缅甸翡翠中硬玉的Fe含量偏低,而危地马拉翡翠中绿辉石的Fe含量较缅甸翡翠中绿辉石的Fe含量偏高。对翡翠外观特征的充分对比和对判别图的综合分析可应用于实际中翡翠产地的区分。  相似文献   

青藏高原东北缘祁连山三叠系砂岩碎屑锆石U-Pb定年及其物源分析     

吴龙  柳长峰  刘文灿  张宏远 《现代地质》2021,35(5):1178-1193

三叠系沉积物广泛覆盖青藏高原东北缘,其中松潘—甘孜地区三叠系的沉积物得到了较系统的研究,但是青藏高原北缘的祁连山三叠系盆地的研究却较为缺乏。为了丰富相关研究和揭示区域构造演化的特点,通过古水流方向统计、砂岩中碎屑矿物统计和碎屑锆石U-Pb测年等方法对祁连山三叠纪盆地物源进行系统研究。结果表明,祁连山三叠系盆地的古流向主要有南东向、正南向、南西向,物源来自岩浆弧和大规模褶皱造山作用的混合区。祁连山三叠系砂岩中的碎屑锆石的年龄谱主要峰值集中在250~290 Ma、360~460 Ma、1 600~2 000 Ma和2 200~2 600 Ma这4个年龄段。通过对比分析华北板块、华南板块中和秦祁昆中央造山带中岩浆锆石年龄谱特征可知:1 600~2 000 Ma和2 200~2 600 Ma年龄段的锆石来自华北板块,360~460 Ma年龄段的锆石来自北祁连造山带,250~290 Ma年龄段的锆石来自东昆仑的火山岛弧。此外,600~1 000 Ma年龄段锆石很少,这些锆石来自扬子板块,表明在三叠纪扬子克拉通和华北克拉通发生碰撞形成了秦岭造山带,阻断了来自扬子克拉通的物源。  相似文献   

鄂尔多斯盆地南部马莲河流域地下水中锶富集特征及成因分析     

李海学  程旭学  马岳昆  刘伟坡  周斌 《现代地质》2021,35(3):682-692

马莲河流域地处鄂尔多斯盆地南部黄土高原区,按储水介质和埋藏条件可将地下水分为黄土潜水、基岩潜水和基岩承压水三类,利用2015—2018年流域的295组地下水水化学数据,分析了地下水中锶(Sr²⁺)的质量浓度水平、垂向分布及沿流向分布的特征,并采用因子相关性研究地下水中Sr²⁺的来源和富集成因。结果表明:马莲河流域地下水富锶现象显著,黄土潜水、基岩潜水和基岩承压水中锶的平均质量浓度分别为1.14 mg/l、1.39 mg/l和5.24 mg/l;地下水中锶富集成因主要是含锶矿物天然状态下的水-岩作用,黄土潜水、基岩潜水和基岩承压水三类地下水中Sr²⁺的主要来源分别为碳酸盐岩与铝硅酸盐岩、碳酸盐岩与硫酸盐和碳酸盐矿物的溶滤作用;地下水中Sr²⁺的质量浓度沿流向呈逐渐增大的趋势,在不同区域中随深度变化的趋势不一致。  相似文献   

Structural Setting and Kinematic Analysis of the Halaban Region,Eastern Arabian Shield,Saudi Arabia     

Osama M. KASSEM  Yousef A. ALAMRI  Faisal K. ZAIDI  Abdel Aziz M. AL BASSAM  Mansour H. AL-HASHIM 《《地质学报》英文版》2021,95(3):750-760

The vorticity analysis technique was applied to measure the different lithological units,such as schist,metagranite and metavolcano-sedimentary rocks,which are present in the Halaban region.This work aims to interpret the relationship between the different lithologies and the tectonic setting,in order to elucidate the nature of kinematic analysis in the Halaban region.The kinematic analyses were applied to feldspar porphyroclasts,quartz and hornblende for twentysix samples.The kinematic vorticity number (W_m) for deformed rocks in the study area ranged from～0.6 to 0.9.The direction of the long axes for finite strain data (X axes) revealed a WNW trend with shallow dipping.The direction of the short axes for finite strain data (Z axes) were represented by vertical with associated horizontal foliation.The results of the kinematic vorticity and strain analyses are characterized by simple shear with different degrees of deformation in the Halaban region.Furthermore,our finite strain data shows no significant volume change during deformation.The subhorizontal foliation was synchronized with thrusting and deformation.Furthermore,throughout the overlying nappes,the same attitudes of tectonic contacts are observable,the nappes in the orogens being formed from simple shear deformation.  相似文献   

Geochemistry and Tectonic History of Seamount Remnants in the Xingshuwa Subduction Accretionary Complex of the Xar Moron Area,Eastern Margin of the Central Asian Orogenic Belt     

CHENG Yang  XIAO Qinghui  LI Tingdong  LI Yan  FAN Yuxu  XU Liquan  GUO Lingju  PANG Jinli 《《地质学报》英文版》2021,95(4):1086-1098

This study focuses on the geology, geochemistry, zircon U-Pb geochronology and tectonic settings of the three types of seamount basalts from the Xingshuwa subduction accretionary complex in the Xar Moron area, eastern margin of the Central Asian Orogenic Belt(CAOB). The seamount remnants are composed of carbonate 'cap' sediments, large volumes of pillow and massive basalts, carbonate breccia slope facies and radiolarian cherts. Group 1 basalts are characterized by high contents of P2 O5 and TiO2 with alkaline affinity and LREE enrichment, indicating that they are derived from intraplate magma. Group 2 basalts display N-MORB LREE depletion patterns, indicating that they were formed at a mid-ocean ridge. Group 3 basalts have shown distinct Nb depletion and high Th/Yb ratios, indicating that they were generated in an island arc tectonic setting. The zircon U-Pb age of Group 1 basalt sample XWT18-131 is 576.4 ± 9.4 Ma, suggesting that the oceanic island seamount was the product of intraplate magmatism related to a mantle plume or 'hot spot' in the late Neoproterozoic. The zircon U-Pb age of Group 2 basalt sample XWT18-132 is 483 ± 22 Ma, indicating that the Paleo-Asian Ocean(PAO) was continuously expanding in the Early Ordovician. The zircon U-Pb age of Group 3 basalt sample XWT18-101 is 240.5 ± 8.2 Ma, suggesting that this area underwent the evolutionary path of ocean-continent transition, developing towards continentalization during the Middle Triassic. Thus, we believe that there was both mantle plume-related intraplate magmatism and intraoceanic subduction during the evolution of the PAO, the CAOB possibly being an evolutionary model of an intraoceanic subduction and mantle plume magmatism complex.  相似文献